WO2002029146A1 - Procede de file-lie (spunbond) a denier fin et produits obtenus selon ce procede - Google Patents

Procede de file-lie (spunbond) a denier fin et produits obtenus selon ce procede Download PDF

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Publication number
WO2002029146A1
WO2002029146A1 PCT/US2001/042475 US0142475W WO0229146A1 WO 2002029146 A1 WO2002029146 A1 WO 2002029146A1 US 0142475 W US0142475 W US 0142475W WO 0229146 A1 WO0229146 A1 WO 0229146A1
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WO
WIPO (PCT)
Prior art keywords
denier
fabric
barrier
layer
fine
Prior art date
Application number
PCT/US2001/042475
Other languages
English (en)
Inventor
Richard Leon Ferencz
Original Assignee
Polymer Group Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polymer Group Inc. filed Critical Polymer Group Inc.
Priority to JP2002532707A priority Critical patent/JP2004510895A/ja
Priority to MXPA03002722A priority patent/MXPA03002722A/es
Priority to CA002423070A priority patent/CA2423070A1/fr
Priority to EP01981822A priority patent/EP1325185A4/fr
Priority to AU2002213439A priority patent/AU2002213439A1/en
Priority to BR0114386-7A priority patent/BR0114386A/pt
Publication of WO2002029146A1 publication Critical patent/WO2002029146A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/02—Layered products comprising a layer of synthetic resin in the form of fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/016—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the fineness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/681—Spun-bonded nonwoven fabric

Definitions

  • the present invention relates generally to a method of continuously extruding essentially endless, thermoplastic polymer, fine denier filaments, and products produced thereby.
  • Nonwoven fabrics embodying the present invention exhibit unique performance attributes, particularly when used in multiple layers, which offer improved barrier characteristics. Incorporation of at least one conventional filament layer onto a fine denier filament layer has resulted in fabrics, which have exhibited enhanced barrier performance in comparison to conventional continuous filament/melt-blown barrier constructs.
  • Nonwoven fabrics are used in a wide variety of applications where the engineered qualities of the fabrics can be advantageously employed.
  • the use of selected thermoplastic polymers in the construction of the fibrous fabric component, selected treatment of the fibrous component (either while in fibrous form or in an integrated structure), and selected use of various mechanisms by which the fibrous component is integrated into a useful fabric, are typical variables by which to adjust and alter the performance of the resultant nonwoven fabric.
  • barrier performance has been enhanced by the use of a barrier melt-blown layer of very fine filaments, which are drawn and fragmented by a high velocity air stream, and deposited into a self-annealing mass.
  • a melt-blown layer exhibits very low porosity, enhancing the barrier properties of composite fabrics formed with spunbond and melt- blown layers.
  • SMS spunbond/melt-blown /spunbond
  • Conventional spunbond/melt-blown /spunbond (SMS)-type fabrics for protective apparel are manufactured in a basis weight range of 60-65 grams per square meter, typically relying upon a melt-blown layer of more than 10 grams per square meter, to provide the desired barrier function.
  • these types of fabrics have a hydrostatic head rating of greater than 45 centimeters, before the addition or topical treatment of the constructs with alcohol resistant and antistatic chemistries.
  • Further prior art improvements on the SMS construct have been made by incorporating multiple light-weight melt-blown barrier layers, i.e. SMMS fabrics, in lieu of single heavy-weight melt-blown layers.
  • Such modifications provide a laminate having improved barrier and strength to weight ratios.
  • the enhancement is measured by the ratio of hydrostatic head to melt-blown layer basis weight of greater than 115 cm/osy (3.38 cm/gsm).
  • the present invention contemplates that the provision of one or more fine denier spunbond layers significantly improves the overall barrier performance of the composite fabric.
  • the fine denier spunbond layer provides a more uniform interface between the spunbond layer and a subsequent barrier layer applied during the manufacture of the nonwoven fabric, resulting in improved barrier performance in the fabricated article.
  • the present invention is directed to a nonwoven composite fabric comprising one or more layers of fine denier spunbond filaments and at least one layer of barrier material, wherein said nonwoven composite fabric has a significantly improved barrier performance as measured by the hydrostatic head to barrier layer basis weight ratio being of about at least 4.9 cm/gsm.
  • first and second outer fabric layers are formed, each comprising continuous filament spunbond layers of thermoplastic fibers, with the size of the continuous filaments between about 0.7 and 1.2 denier, preferably less than or equal to 1 denier.
  • the barrier layer preferentially comprises microfibers of finite length, wherein the average fiber diameter is in the range of about 1 micron to about 10 microns, and preferably between about 1 micron and 5 microns, said layers being consolidated into a composite fabric.
  • thermoplastic polymers of the continuous filament spunbond layer or layers are chosen from the group consisting of polyolefins and polyesters, wherein the polyolefins are chosen from the group consisting of polypropylene, polyethylene, and combinations thereof. It is within the purview of the present invention that the continuous filament spunbond layer or layers may comprise either the same or different thermoplastic polymers. Further, the continuous filaments of the spunbond layer or layers may comprise homogeneous, bicomponent, and/or multi-component profiles and the blends thereof.
  • the barrier layer comprises a material selected from suitable media, such media include: melt-blown, cellulosic pulp, microporous film or monolithic film, with a microfiber media such as melt-blown being preferred.
  • suitable media include: melt-blown, cellulosic pulp, microporous film or monolithic film, with a microfiber media such as melt-blown being preferred.
  • the thermoplastic polymers of the melt-blown microfibers are chosen from the group consisting of polyolefins and polyesters, wherein the polyolefins are chosen from the group consisting of polypropylene, polyethylene, and combinations thereof. It is within the purview of the present invention that the microfibers may comprise either the same or different thermoplastic polymers. Further, the microfibers may comprise homogeneous, bicomponent, and/or multi-component profiles and the blends thereof.
  • the melt-blown layer is in the basis weight range of less than or equal to about 10 grams per square meter, the basis weight of between 1 and 8 grams per square meter
  • formation of a composite fabric structure entails the formation of first and second outer, spunbond web layers, and plural barrier melt-blown layers, for example, two, melt-blown barrier layers.
  • each of the outer, spunbond web layers are formed from a plurality of endless filaments having a denier of between 0.7 and 1.2 denier, with each outer layer preferably formed with the same basis weight, and from the same denier filaments.
  • Formation of plural barrier melt-blown layers can be effected such that each of the melt-blown layers is formed to have the same basis weight.
  • the incorporation of fine denier spunbond layers provide substantial improvement in barrier function, allowing for reduction in the amount of the spunbond and /or barrier layer required to meet performance criteria.
  • the fine denier spunbond layer provides a more uniform support layer for the barrier layer during the manufacturing process providing substantial improvement in barrier function in the resulting end-use articles.
  • Formation of fabrics from fine denier spunbond materials, particularly when combined with one or more barrier melt-blown layers, has been found to provide enhanced barrier properties.
  • the present invention allows the production of a same weight fabric with improved barrier properties or a lighter weight fabric that is suitable for use as a barrier fabric, particularly for medical gowns and industrial protective apparel. Use of the present fabric as a battery separator component is also contemplated.
  • FIGURE 1 is a plan view of a diaper embodying this invention, the diaper being shown in an uncontracted state.
  • FIGURE 2 is an elevation of a surgical gown embodying this invention. Detailed Description
  • the present invention is directed to a nonwoven composite fabric, which entails formation of a layer of fine denier spunbond filaments and at least one layer of barrier material.
  • the spunbond filaments preferably have a denier in the range of about 0.7 to 1.2, and preferably have a denier less than or equal to about 1.
  • a spunbond process involves supplying a molten polymer, which is then extruded under pressure through a large number of orifices in a plate known as a spinneret or die.
  • the resulting continuous filaments are quenched and drawn by any of a number of methods, such as slot draw systems, attenuator guns, or
  • Godet rolls The continuous filaments are collected as a loose web upon a moving foraminous surface, such as a wire mesh conveyor belt.
  • a moving foraminous surface such as a wire mesh conveyor belt.
  • the subsequent webs is collected upon the uppermost surface of the previously formed web.
  • the web is then at least temporarily consolidated, usually by means involving heat and pressure, such as by thermal point bonding.
  • thermal point bonding Using this bonding means, the web or layers of webs are passed between two hot metal rolls, one of which has an embossed pattern to impart and achieve the desired degree of point bonding, usually on the order of 10 to 40 percent of the overall surface area being so bonded.
  • thermoplastic polymers of the continuous filament spunbond layer or layers are chosen from the group consisting of polyolefins and polyesters, wherein the polyolefins are chosen from the group consisting of polypropylene, polyethylene, and combinations thereof. It is within the purview of the present invention that the continuous filament spunbond layer or layers may comprise either the same or different thermoplastic polymers. Further, the continuous filaments of the spunbond layer or layers may comprise homogeneous, bicomponent, and/or multi-component profiles and the blends thereof.
  • the barrier layer comprises a material selected from suitable media, such media include: melt-blown, cellulosic pulp, microporous film or monolithic film, with microfiber media such as melt-blown being preferred.
  • suitable media include: melt-blown, cellulosic pulp, microporous film or monolithic film, with microfiber media such as melt-blown being preferred.
  • Cellulosic pulp barrier layers are well-known for providing a useful barrier performance in medical applications and include such materials as wood pulp, in either a wetlaid tissue form or as an airlaid fibrous layer.
  • Suitable microporous film barrier layer can include materials such as those reported in U.S. Patent No. 5,910,225, the disclosure of which is herein incorporated by reference, in which pore- nucleating agents are used to form the micropores.
  • Monolithic films as reported in U.S. Patent No.
  • a preferred mechanism for forming a barrier layer is through application of the melt-blown process.
  • the melt-blown process is a related means to the spunbond process for forming a layer of a nonwoven fabric, wherein, a molten polymer is extruded under pressure through orifices in a spinneret or die. High velocity air impinges upon and entrains the filaments as they exit the die. The energy of this step is such that the formed filaments are greatly reduced in diameter and are fractured so that microfibers of finite length are produced. This differs from the spunbond process whereby the continuity of the filaments is preserved.
  • the process to form either a single layer or a multiple-layer fabric is continuous, that is, the process steps are uninterrupted from extrusion of the filaments to form the first and subsequent layers through consolidation of the layers to form a composite fabric.
  • the fine-fiber spunbond material is made by decreasing the extrusion rate, while increasing the rate of the filaments.
  • a thermoplastic polymer can be selected to provide adequate melt strength so as to minimize fiber ' breaks during the fiber draw-down process.
  • melt-blown process as well as the cross-sectional profile of the spunbond filament or melt-blown microfiber are not a critical limitation to the practice of the present invention.
  • a fine denier spunbond layer upon which the melt-blown layer is deposited, several enhancements of the fabric are realized.
  • a finer denier fabric will give a greater number of filaments and a smaller average pore size.
  • the smaller average pore size will result in a more uniform deposition of the melt-blown microfibers onto the spunbond layer.
  • a more uniform melt-blown layer will have fewer weak points in the web at which a failure in barrier performance can occur.
  • the spunbond layer also serves to support the melt-blown layer structurally in the composite material.
  • a finer denier spunbond layer provides a smaller average pore size and a larger number of support points for the barrier layer; this results in shorter spans of unsupported melt-blown microfibers. This mechanism embodies the well-known concept that reduction in the average span length results in enhanced structural integrity. Examples
  • Example 1 is a conventional SMS fabric comprising a spunbond layer basis weight being 17 gsm and a melt-blown basis weight being 10 gsm. This construct was made in accordance with standard practices as applied to equipment supplied by Reifenhauser GmbH for the formation of fabric by thermal point bonding in a diamond pattern at a coverage area of 17%.
  • a thermoplastic resin was provided in the form of polypropylene 3155 available from Exxon Corporation.
  • Example 2 is a conventional SMMS fabric comprising a spunbond layer basis weight being 15 gsm and a melt-blown basis weight being 7.5 gsm. This construct was made in accordance with standard practices as applied to equipment supplied by Reifenhauser GmbH for the formation of fabric by thermal point bonding in a diamond pattern at a coverage area of 17%.
  • a thermoplastic resin was provided in the form of polypropylene 3155 available from Exxon Corporation.
  • Example 3 is an SMS fabric made in accordance with the present invention, comprising a spunbond layer basis weight being 17 gsm and a melt- blown basis weight being 8 gsm.
  • the polypropylene resin used to form the spunbond layer was Achieve® 3854 available from Exxon Corporation. This construct was made in accordance with standard practices as applied to equipment supplied by Reifenhauser GmbH for the formation of fabric by thermal point bonding in an oval pattern at a coverage area of 18%.
  • Example 4 is an SMMS fabric made in accordance with the present invention, comprising a spunbond layer basis weight being 10 gsm and amelt- blown basis weight being 5 gsm.
  • the polypropylene resin used to form the spunbond layer was Achieve® 3854 available from Exxon Corporation. This construct was made in accordance with standard practices as applied to equipment supplied by Reifenhauser GmbH for the formation of fabric by thermal point bonding in an oval pattern at a coverage area of 18%.
  • Example 5 is an SMMS fabric made in accordance with the present invention, comprising a spunbond layer basis weight being 17 gsm and a melt- blown basis weight being 8 gsm.
  • the polypropylene resin used to form the spunbond layer was Achieve® 3854 available from Exxon Corporation. This construct was made in accordance with standard practices as applied to equipment supplied by Reifenhauser GmbH for the formation of fabric by thermal point bonding in an oval pattern at a coverage area of 18%.
  • Example 6 is an SMMS fabric made in accordance with the present invention, comprising a spunbond layer basis weight being 6 gsm and a melt- blown basis weight being 2.5 gsm.
  • the polypropylene resin used to form the spunbond layer was Achieve® 3854 available from Exxon Corporation. This construct was made in accordance with standard practices as applied to equipment supplied by Reifenhauser GmbH for the formation of fabric by thermal point bonding in an oval pattern at a coverage area of 18%.
  • Example 7 is an SMS fabric made in accordance with the present invention, comprising a spunbond layer basis weight being 7 gsm and a melt- blown basis weight being 3 gsm.
  • the polypropylene resin used to form the spunbond layer was Achieve® 3854 available from Exxon Corporation. This construct was made in accordance with standard practices as applied to equipment supplied by Reifenhauser GmbH for the formation of fabric by thermal point bonding in an oval pattern at a coverage area of 18%.
  • Comparative sample A is a polypropylene SMS fabric described in U.S. Patent No. 5,464,688.
  • Comparative sample B is a polypropylene SMS fabric described in U.S. Patent No. 5,482,765.
  • Table 1 sets forth composite fabrics formed in accordance with the present invention compared to conventional SMS and SMMS fabrics. Testing was done in accordance with the following standard test methods.
  • the regular denier SMS material (Example 1) is shown as having layers formed with various individual basis weights of 17 gsm/10 gsm/17 gsm.
  • the denier of the spunbond layer was measured by common technique and was found to be 1.7 denier.
  • the melt-blown fiber diameters were measured to give an average of 2.0 microns.
  • An SMMS material (Example 2) is also shown in Table 1, as having layers formed with various individual basis weights of 15 gsm/7.5gsm/7.5 gsm/15 gsm.
  • the spunbond layers have filaments of 2.3 denier and the average melt-blown diameter is 2.8 microns.
  • the conventional SMS and SMMS fabrics exhibit hydrostatic head values of 36.8 and 53 cm respectively.
  • Example 3 represents a polypropylene SMS fabric made in accordance with the invention, with individual layers of the following basis weights, 17 gsm/8 gsm/17 gsm.
  • the denier of the spunbond layer was measured by common technique and was found to be 1.0 denier.
  • the melt-blown fiber diameters were measured to give an average of 2.1 microns.
  • the hydrostatic head to basis weight ratio for the fabric of Example 3 is 6.1.
  • the improvement of barrier property in the material made in accordance with this invention as measured by hydrostatic head represents a 65% increase per gram per square meter of the melt-blown barrier layer.
  • Example 4 represents a polypropylene SMMS fabric made in accordance with the invention, with individual layers of the following basis weights, 10 gsm/5 gsm/5 gsm/10 gsm.
  • the denier of the spunbond layer was measured by common technique and was found to be 1.1 denier.
  • the melt-blown fiber diameters were measured to give an average value of 1.9 microns.
  • the hydrostatic head to basis weight ratio for the fabric of Example 4 is 4.9 cm/gsm.
  • the improvement of barrier property in the material made in accordance with this invention as measured by hydrostatic head represents a 40% increase per gram per square meter of the melt-blown barrier layer.
  • Example 5 represents a polypropylene SMMS fabric made in accordance with the invention, with individual layers of the following basis weights, 17 gsm/8 gsm/8 gsm/17 gsm.
  • the hydrostatic head value for this fabric is 90 cm, making this material suitable for use in medical applications such as medical gowns.
  • Examples 6-7 demonstrate the high ratio of hydrostatic head to melt-blown basis weight, 7.4 and 7.8 cm/gsm respectively, in lightweight constructs as embodied in the present invention. Such lightweight constructs are particularly advantageous when used in the fabrication of end-use articles requiring significant barrier performance.
  • Disposable waste-containment garments are generally described in U.S. Patents No. 4,573,986, No. 5,843,056, and No. 6,198,018, the disclosures of which are incorporated herein by reference.
  • FIG. 1 is a plan view of a diaper 20 in an uncontracted state (i.e., with elastic induced contraction pulled out) with portions of the structure being cutaway to more clearly show the construction of the diaper 20. As shown in FIG.
  • the diaper 20 preferably comprises a containment assembly 22 comprising a liquid pervious topsheet 24; a liquid impervious backsheet 26 joined to the topsheet; and an absorbent core 28 positioned between the topsheet 24 and the backsheet 26.
  • the absorbent core 28 has a pair of opposing longitudinal edges, an inner surface and an outer surface.
  • the diaper can further comprise elastic leg features 32; elastic waist features 34; and a fastening system 36, which preferably comprises a pair of securement members 37 and a landing member 38.
  • Practical application of an improved barrier fabric as described in this invention for backsheet 26 results in a diaper that is lighter in weight while maintaining performance.
  • a lighter weight backsheet material is expected to be more flexible and therefore more conforming to deformation of the overall structure as the diaper is worn.
  • Catamenial products such as feminine hygiene pads, are of the same general construction as the aforementioned diaper structure. Again, a topsheet and a backsheet are affixed about a central absorbent core. The overall design of the catamenial product is altered to best conform to the human shape and for absorbing human exudates.
  • Representative prior art to such article fabrication include U.S. Patents No. 4,029,101, No. 4,184,498, No. 4,195,634, No.
  • a disposable garment generally designated 110 comprising a surgical gown 112.
  • the gown 112 comprises a body portion 114, which may be one-piece, having a front panel 116 for « ⁇ covering the front of the wearer, and a pair of back panels 118 and 120 extending from opposed sides of the front panel 116 for covering the back of the wearer.
  • the back panels 118 and 120 have a pair of side edges 122 and 124, respectively, which define an opening on the back of the gown.
  • the gown 112 has a pair of sleeves 126 and 128 secured to the body portion 114 of the gown for the arms of the wearer.
  • the back panels 118 and 120 overlap on the back of the wearer in order to close the back opening of the gown, and suitable belt means (not shown) is utilized to secure the back panels 118 and 120 in the overlapping relationship.
  • SMS composite fabric is routinely used as a battery separator between the positive and negative plates of a battery cell in order to inhibit physical contact between the two opposing plates.
  • the battery separator must allow for the free flow of electrons that are produced due to the chemical activity within the cell, but must also provide a barrier such that any active paste-like substances are prevented from penetrating the separator material.
  • lighter weight and less bulky fabrics may be employed, for example, as battery separators. Less bulky fabrics allow for closer spacing of the anode and cathode and an increase in the active material in the battery for a given volume.

Abstract

L'invention concerne un textile non tissé comprenant une ou plusieurs couches de filé-lié à denier fin et une ou plusieurs couches barrière. Chaque couche de filé-lié à denier fin comprend des filaments continus ayant un denier compris entre 0,7 et 1,2, ces filaments étant choisis parmi des polyesters, des polyoléfines et des mélanges de ces derniers.
PCT/US2001/042475 2000-10-06 2001-10-05 Procede de file-lie (spunbond) a denier fin et produits obtenus selon ce procede WO2002029146A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2002532707A JP2004510895A (ja) 2000-10-06 2001-10-05 細いデニールの繊維のスパンボンド法およびその製品
MXPA03002722A MXPA03002722A (es) 2000-10-06 2001-10-05 Proceso de extruido y estirado con denier fino y sus productos.
CA002423070A CA2423070A1 (fr) 2000-10-06 2001-10-05 Procede de file-lie (spunbond) a denier fin et produits obtenus selon ce procede
EP01981822A EP1325185A4 (fr) 2000-10-06 2001-10-05 Procede de file-lie (spunbond) a denier fin et produits obtenus selon ce procede
AU2002213439A AU2002213439A1 (en) 2000-10-06 2001-10-05 Fine denier spunbond process and products thereof
BR0114386-7A BR0114386A (pt) 2000-10-06 2001-10-05 Processo de ligação por fiação de denier fino e produtos do mesmo

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US23849700P 2000-10-06 2000-10-06
US60/238,497 2000-10-06

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JP (1) JP2004510895A (fr)
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CA (1) CA2423070A1 (fr)
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US7070884B2 (en) 2001-10-09 2006-07-04 Polymer Group, Inc. Separator with improved barrier performance
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GB2518055A (en) * 2014-08-22 2015-03-11 Don & Low Ltd Improved fabric
GB2518055B (en) * 2014-08-22 2015-08-12 Don & Low Ltd Improved fabric
GB2525103A (en) * 2014-08-22 2015-10-14 Don & Low Ltd Improved fabric
GB2525103B (en) * 2014-08-22 2016-06-08 Don & Low Ltd Improved fabric

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BR0114386A (pt) 2004-02-03
JP2004510895A (ja) 2004-04-08
US20020142692A1 (en) 2002-10-03
MXPA03002722A (es) 2005-04-19
CA2423070A1 (fr) 2002-04-11
EP1325185A1 (fr) 2003-07-09
AU2002213439A1 (en) 2002-04-15
EP1325185A4 (fr) 2004-09-29

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